Electrochemical promotion of propane oxidation on Pt deposited on a dense β″-Al2O3 ceramic Ag+ conductor

نویسندگان

  • Mihalis N. Tsampas
  • Anastasios Kambolis
  • Emil Obeid
  • Leonardo Lizarraga
  • Foteini M. Sapountzi
  • Philippe Vernoux
چکیده

A new kind of electrochemical catalyst based on a Pt porous catalyst film deposited on a β″-Al2O3 ceramic Ag(+) conductor was developed and evaluated during propane oxidation. It was observed that, upon anodic polarization, the rate of propane combustion was significantly electropromoted up to 400%. Moreover, for the first time, exponential increase of the catalytic rate was evidenced during galvanostatic transient experiment in excellent agreement with EPOC equation.

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عنوان ژورنال:

دوره 1  شماره 

صفحات  -

تاریخ انتشار 2013